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39. "Photoelectrochemical Hetereodifunctionalization of Olefins: Carboamidation Using Unactivated Hydrocarbons"

S. Schmid, S. Wu, I. Dey, M. Domanski, X. Tian,* J. P. Barham,*

ACS Catal. 2024, 14, 9648-9654

acspectoc

 

38. "Protodefluorinated Selectfluor Promotes Aggregative Activation of Selectfluor for Efficient C(sp3)-H Fluorination Reactions"

S. Yakubov, B. Dauth, W. Stockerl, W. M. da Silva, R. M. Gschwind,* J. P. Barham*

ChemSusChemaccepted manuscript.

ChemRxiv. 2024 (Preprint), DOI: 10.26434/chemrxiv-2023-3t26g   PDF

SFHTOC

 

37. "Electrochemical Homo- and Cross-Annulation of Alkynes and Nitriles for the Regio- and Chemoselective Synthesis of 3,6-Diarylpyridines"

M. Ghosh, T. Mandal, M. Lepori, J. P. Barham, J. Rehbein, J. P. Barham, O. Reiser*

ChemRxiv. 2024 (Preprint), DOI: 10.26434/chemrxiv-2024-h5m89   PDF

Mangish



36.
 
"A hydrazine-free photoredox catalytic synthesis of azines by reductive activation of readily available oxime esters"

J. Schütte, D. Corsi, W. Haumer, S. Schmid, J. Zurauskas, J. P. Barham*

Green Chem. 2024, Advance Article   PDF

(Selected for the Inside Front Cover of Issue 11, 2024)

GC_JS_TOC

 

 

35. "An affordable, programmable and interactive continuous flow Photoreactor setup for undergraduate organic synthetic teaching labs"

M. Domanski, G. Marcou,* J. P. Barham*

J. Flow Chem. 2024, DOI: 10.1007/s41981-023-00306-9   PDF

TOCJFC

 

 

34. "Photo- and electro-chemical strategies for the activations of strong chemical bonds"

X. Tian, Y. Liu, S. Yakubov, J. Schütte, S. Chiba,* J. P. Barham*

Chem. Soc. Rev. 2024, 53, 263-316   PDF

 

 

33. "Electron-Poor Acridones and Acridiniums as Super Photooxidants in Molecular Photoelectrochemistry by Unusual Mechanisms"

J. Zurauskas, S. Bohacova, S. Wu, V. Butera, S. Schmid, M. Domanski, T. Slanina, J. P. Barham*

Angew. Chem., Int. Ed. 2023, e202307550    PDF

TOCAcridones

 

 

32. "Solvent Dependency of Catalyst-Substrate Aggregation Through π-π Stacking in Photoredox Catalysis"

L. Wylie,* J. P. Barham,* B. Kirchner

ChemPhysChem 2023, e202300470    PDF

LWpaperTOC         LWpaper1

 

 

31. "Photoredox Catalysis Harvesting Multiple Photon or Electrochemical Energies"

M. Lepori, S. Schmid, J. P. Barham,*

Beilstein J. Org. Chem. 2023, 19, 1055-1145    PDF

(Invited contribution "Thematic Issue: Artificial photosynthesis" by Prof. Andrea Pannwitz. Editor's Pick)

BJOCconPETTOC

 

30. "Shining Fresh Light on Complex Photoredox Mechanisms Through Isolation of Intermediate Radical Anions"

S. Horsewill, G. Hierlmeier, Z. Farasat, J. P. Barham, D. J. Scott,*

ACS Catal. 2023, 13, 9392-9403    PDF

    Scottpaper             scottpaper2

 

29. "Transient absorption spectroscopy based on an uncompressed hollow core fiber whitelight proves pre-association between a radical ion photocatalyst and substrate"

A. Kumar, P. Malecvich, L Mewes, S. Wu, J. P. Barham, J. Hauer,*

J. Phys. Chem. 2023, 158, 144201    PDF

TOCJChemPhys

28. "Organophotocatalytic Mechanisms: Simplicity of Naïvety? Diverting Reactive Pathways by Modifications of Catalyst Structure, Redox States, Substrate Preassemblies & Static Quenching"

M. J. P. Mandigma, J. Kaur, J. P. Barham,*

ChemCatChem 2023, 11, e202201542    PDF

(Invited contribution "Special Issue: Photocatalysis" by Prof. Oliver Wenger/Dr. Bart Pieber/Dr. Line Næsborg. Editor's Choice: Spotlights Photocatalytic Synthesis - Catalysts, Catalytic Strategies, and Mechanistic Insights)

TOCCCC
FrontisCCC

27. "Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(sp3)-H fluorinations"

S. Yakubov, W. J. Stockerl, X. Tian, A. Shahin, M. J. P. Mandigma, R. M. Gschwind, J. P. Barham,*

Chem. Sci. 2022, 13, 14041-14051    PDF

(Selected as a Outside Back Cover for issue 47, 2022)

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tocChemSciSY

 

26. "A Tunable Microwave Flow System for Scalable Synthesis of Alkyl Imidazolium-type Ionic Liquids"

M. Domanski, J. Zurauskas, J. P. Barham,*

Org. Process Res. Dev. 2022, 26, 2498-2509    PDF

(Selected as a Supplementary Cover for Issue 8, 2022)

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ILTOC


25.
 "α-amino Radical Halogen Atom Transfer Agents for Metallaphotoredox Catalyzed Cross Electrophile Couplings of Distinct Organic Halides"

X. Tian, J. Kaur, S. Yakubov, J. P. Barham,*

ChemSusChem 2022, 15, e202200906     PDF

(Reader's choice article, July 2022. Selected for Wiley 'Hot Topic': C-C coupling. Selected for Wiley 'Hot Topic': Photocatalysis)



24.
 "Site-selective C(sp3)-H Functionalizations Mediated by Hydrogen Atom Transfer Reactions via α-amino/α-Amido Radicals"

J. Kaur, J. P. Barham,*

Synthesis 2022, 54, 1461-1477    PDF

(Invited contribution by Prof. Paul Knochel/Prof. Martin Oestreich)

TOCSynthesisRevHAT3

23. "An Organophotocatalytic Late-stage N-CH3 Oxidation of Trialkylamines to N-formamides with O2 in Continuous Flow"

M. J. P. Mandigma, J. Zurauskas, C. I. MacGregor, L. J. Edwards, A. Shahin, L. d'Heureuse, P. Yip, D. J. S. Birch, T. Gruber, J. Heilmann, M. P. John, J. P. Barham*

Chem. Sci. 2022, 13, 1912-1924     PDF

(Selected for the Outside Back Cover for Issue 7, 2022. Selected for the Themed Collection: 'Most popular 2021 catalysis articles'. Presentation of this work by M. J. P. Mandigma was recognized by awards: FameLab Bayern '1st place'; EYCheM2022 'best talk')


coverSubDCAS

TOCDCAS

22. "Synthetic Molecular Photoelectrochemistry: New Frontiers in Synthetic Applications, Mechanistic Insights and Scalability"

S. Wu, J. Kaur, T. A. Karl, X. Tian, J. P. Barham*

Angew. Chem., Int. Ed. 2021, 61, e202107811    PDF

(Selected for the Inside Front Cover for Issue 12)

TOCACIErev2

 

SynthMolPEC

21. "Catalyst-free, Scalable Heterocyclic Flow Photocyclopropanation"

V. Klöpfer, R. Eckl, J. Floß, P. M. C. Roth, O. Reiser,* J. P. Barham*

Green Chem. 2021, 23, 6366-6372    PDF

 (Selected for the Outside Front Cover for Issue 17, 2021. Selected as a 2021 Green Chemistry 'HOT Article')

WaterfallGC

GChemTOC

20. "Electro-mediated PhotoRedox Catalysis for Selective C(sp3)-O Cleavages of Phosphinated Alcohols to Carbanions"

X. Tian, T. Karl, S. Reiter, S. Yakubov, R. de Vivie-Riedle, B. König,* J. P. Barham*

Angew. Chem., Int. Ed. 2021, 60, 20817-20825    PDF

TOCphosphin

19. "Hole-Mediated PhotoRedox Catalysis: Tris(p-Substituted)biarylaminium Radical Cations as Tunable, Precomplexing and Potent Photooxidants"

S. Wu, J. Zurauskas, M. Domanski, P. Hitzfeld, V. Butera, D. J. Scott, J. Rehbein, A. Kumar, E. Thyrhaug, J. Hauer, J. P. Barham* 

Org. Chem. Front. 2021, 8, 1132-1142     PDF

(Selected for the Outside Back Cover for Issue 6, 2021; ESI 'Highly Cited' paper in 2021)

OCF cover Ar3N

 OCF TOC Ar3N

18. "Photocatalyst-Free, Visible-Light-Mediated C(sp3)-H Arylation of Amides via a Solvent-Caged EDA Complex"

J. Kaur, A. Shahin, J. P. Barham*

Org. Lett. 2021, 6, 2002-2006     PDF

(Selected as a Supplementary Cover for Issue 6, 2021)

OL EDA cover

OL EDA TOC

17. "Photocatalytic (Hetero)Arylation of C(sp3)-H Bonds with Carbon Nitride" 

S. Das, K. Murugesan, G. J. V. Rodríguez, J. Kaur, J. P. Barham, A. Savateev, M. Antonietti, B. König,*

ACS Catal. 2021, 11, 1593-1603     PDF

TOCACSCatal

(Highlighted in Synfacts by Profs. Y. Uozumi and S. Okumura. ESI 'Highly Cited' paper in 2021 & 2022)

16. "C-Alkylation of alkali metal carbanions with olefins"

M. J. P. Mandigma, M. Domanski, J. P. Barham,*

Org. Biomol. Chem. 202018, 7697-7723     PDF 

(Selected as the Outside Front Cover for Issue 39, 2020)

CAMCOsCoverOBC

TOC_CAMCOs

15. "Photosensitized direct C-H fluorination and trifluoromethylation in organic synthesis"

S. Yakubov, J. P. Barham,*

Beilstein J. Org. Chem. 2020, 16, 2151-2192     PDF TOC photofluor

14. "Base-catalyzed C-alkylation of potassium enolates with styrenes via a Metal-ene Reaction: A Mechanistic Study"

J. P. Barham,* T. Fouquet, Y. Norikane, 

Org. Biomol. Chem. 2020, 18, 2063-2075  PDF 

(Selected as the Outside Front Cover for Issue 11, 2020)

OBC CAKES front cover

 OBC CAKES TOC

13. "Synthetic Photoelectrochemistry" 

J. P. Barham,* B. König, 

Angew. Chem., Int. Ed. 2020, 59, 11732-11747    PDF

(Invited contribution) (ESI Highly Cited paper (top 1% of its academic field) until present)

TOCSynthPECrevcircular

PECreviewTOC

12. "High Efficiency Microwave Flow Chemistry Toward Synthesis of Functional Materials and Pharmaceutical Cores"

J. P. Barham,* E. Koyama, J. Sugiyama, Y. Norikane, H. Egami, Y. Hamashima, 

AMPERE 2019, 17th International Conference on Microwave and High Frequency Heating, In Press    PDF

AMPERE TOC

11. "Microwave Flow: A Perspective on Reactor and Microwave Configurations and the Emergence of Tunable Single-mode Heating Towards Large-scale Applications"

J. P. Barham,* E. Koyama, Y. Norikane, N. Ohneda, T. Yoshimura,* 

Chem. Rec. 2019, 19, 188-203    PDF 

Chem Rec MWflow Cover

10. "A Continuous-Flow Resonator-Type Microwave Reactor for High-Efficiency Organic Synthesis and Claisen Rearrangement as a Model Reaction"

E. Koyama,* N. Ito, J. Sugiyama, J. P. Barham, Y. Norikane, N. Ohneda, Y. Ohno, T. Yoshimura, H. Odajima, T. Okamoto, 

J. Flow Chem. 20188, 147-156    PDF 

JFC cover created

9. "C-alkylation of N-alkylamides with styrenes in air and scale-up using a microwave flow reactor"

J. P. Barham,* S. Tamaoki, H. Egami, N. Ohneda, T. Okamoto, H. Odajima, Y. Hamashima,* 

Org. Biomol. Chem. 201816, 7568-7573    PDF 

OBC C-alk amide flow TOC

8. "Regio- and chemoselective Csp3-H arylation of benzylamines by single electron transfer/hydrogen atom transfer synergistic catalysis"

T. Ide, J. P. Barham, M. Fujita, Y. Kawato, H. Egami, Y. Hamashima,*

Chem. Sci. 2018, 9, 8453-8460    PDF

ChemSci SET HAT TOC

7. "Dual Roles for Potassium Hydride in Haloarene Reduction: CSNAr and SET Reduction via Organic Electron Donors Formed in Benzene"

J. P. Barham, S. E. Dalton, M. Allison, G. Nocera, A. Young, M. P. John, T. M. McGuire, S. Campos, T. Tuttle,* J. A. Murphy,*

J. Am. Chem. Soc. 2018, 140, 11510-11518     PDF 

JACS KH TOC

6. "Selective, Scalable Synthesis of C60-Fullerene/Indene Monoadducts Using a Microwave Flow Applicator"

J. P. Barham,* S. Tanaka, E. Koyama, N. Ohneda, T. Okamoto, H. Odajima, J. Sugiyama, Y. Norikane,* 

J. Org. Chem. 2018, 83, 4348-4354    PDF 

JOC Fullerene TOC

5. "Contra-thermodynamic Hydrogen Atom Abstraction in the Selective C-H Functionalization of Trialkylamine N-CH3 Groups"

J. P. Barham, M. P. John, J. A. Murphy,*

J. Am. Chem. Soc. 2016, 138, 15482-15487    PDF

(Featured in the top 20 ‘most read articles’ of JACS in 2016. Recognised by the 2017 Reaxys Ph.D. Prize)

JACS DABCO TOC

4. "KOtBu: A Privileged Reagent for Electron Transfer Reactions?"

J. P. Barham, G. Coulthard, K. J. Emery, E. Doni, F. Cumine, G. Nocera, M. P. John, L. E. A. Berlouis, T. McGuire, T. Tuttle,* J. A. Murphy,*

J. Am. Chem. Soc. 2016, 138, 7402-7410     PDF

(Featured in the top 20 ‘most read articles’ of JACS in 2016. Features on the first page of Google Entries for ‘KOtBu’. ESI ‘Highly Cited' Paper (top 1% of its academic field) until present)

JACS KOtBu TOC

3. "Double Deprotonation of Pyridinols Generates Potent Organic Electron-Donor Initiators for Haloarene-Arene Coupling"

J. P. Barham, G. Coulthard, R. G. Kane, N. Delgado, M. P. John, John A. Murphy,*

Angew. Chem., Int. Ed. 2016, 55, 4492-4496    PDF  

(Featured in the top 15 ‘most accessed articles’ of ACIE in 03.2016)

ACIE Pyridinols TOC

2. "Asymmetric Intramolecular Conjugate Addition Nitro-Mannich Route to cis-2-Aryl-3-nitrotetrahydroquinolines"

J. C. Anderson,* J. P. Barham, C. D. Rundell,

Org. Lett. 2015, 17, 4090-4093    PDF 

OL NitroMannich TOC

1. "One-pot Functionalisation of N-Substituted Tetrahydroisoquinolines by Photooxidation and Tunable Organometallic Trapping of Iminium Intermediates"

J. P. Barham, M. P. John, J. A. Murphy,*

Beilstein J. Org. Chem. 2014, 10, 2981-2988    PDF 

BJOC THIQ TOC


Book Chapters


1. "Heating Applications: Flow Chemistry"

J. P. Barham,* E. Koyama, Y. Norikane, T. Yoshimura,*

in "RF Power Semiconductor Generator Application in Heating and Energy Utilization" 

Editors: S. Horikoshi, N. Serpone, 2020, pp 91-117, ISBN: 978-981-15-3546-5 

BookChapterHorikoshiCover


 Patents


2. "Title tba"

S. Yakubov, B. Deuth, W. Stockerl, R. M. Gschwind, J. P. Barham

European Patent Office (Applicant: University of Regensburg. Application Number: EP 23 205 559 0. Filing Date: 24.10.2023)

 

1. "Photoresponsive azo compound and polymer compound"

Y. Yue, Y. Norikane, E. Koyama, J. P. Barham

Japan Patent Office (Applicant: National Institute of Advanced Industrial Science and Technology. Institution Number: 301021533. Application Number: PCT/JP2019/010828. Filing Date: 19/02/2019)


Press Releases


2. "Low Volume, High Value"

University of Regensburg Press Release,
01/04/2023.

A personal career journey press release.

For the Press Release (English)


1. "Enabling High-efficiency Synthesis of Organic Materials with a Flow-type Microwave Synthesiser"

National Institute of Advanced Industrial Science and Technology (AIST) Press Release, 12/04/2018.

A research-based press release.

For the Summary (English)

For the Press Release (Japanese)

(Featured in newspaper: Kagaku Kogyou Nippou (Japan Chemical Daily), 13/04/2018, 1st page. Featured in Nikkei Sangyo Shimbun, 19/04/2018, 5th page)


Blogs & Webinars


3. "Hole-mediated PhotoRedox Catalysis: Triarylamine Radical Cations as Tunable, Precomplexing and Potent Photooxidants"

J. P. Barham (Organic Chemistry Frontiers Blog)

For the Blog

2. "Seven strategies for scientists fo communicate their research and create a brand" 

J. P. Barham (Elsevier)

For the Webinar

For the Summary

1. "Exploring continuous flow chemistry"

J. P. Barham (Elsevier)

For the Blog

  1. Fakulty of Chemistry and Pharmacy
  2. Institute of Organic Chemistry

Dr.
Joshua Barham

Joshua-Philip.Barham[at]ur.de

Contact

Sofja Kovalevskaja Group Leader

Office: CH 23.2.80

Phone +49 (0)941 943-4373
E-mail