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Publications

2017

The Case of Homotopic vs. Heterotopic: Kinetic Insight into Catalytic Mechanisms,
D. Gärtner, A. Jacobi von Wangelin, submitted.

Reductive Silylations of Arenes, E. Reyes-Rodriguez, S. Gülak, A. Jacobi von Wangelin.

Stereoselective Photo-Oxygenations by the Schenk Ene reaction,
R. Perez-Ruiz, J. Schachtner, A. Jacobi von Wangelin, submitted.

Stereoselective Photooxidation of Cyclohexenes: The Imperative of Conformational Control,
J. Schachtner, M. Majek, R. Fichtler, R. Perez-Ruiz, J. Regensburger, M. Wegmann, W. Bäumler, T. Bach, A. Jacobi von Wangelin.

Author Profile: Axel Jacobi von Wangelin
Angew. Chem. Int. Ed. 2017, 5610.1002/anie.201708512.

C=C Hydrogenations with Iron Group Metal Catalysts,
T. N. Gieshoff, A. Jacobi von Wangelin, In Non-noble Metal Catalysis: Molecular Approaches and Reactions; B. K. Gebbink, M.-E. Moret, Eds.; Wiley-VCH: New York, 2017.

Metal-Free Radical Aromatic Carbonylations Mediated by Very Weak Bases,
D. Koziakov, A. Jacobi von Wangelin, Org. Biomol. Chem. 2017, 15, 6715.

Synthesis and Catalysis of Redox-active Bis(imino)acenaphthene (BIAN) Iron Complexes,
M. Villa, D. Miesel, A. Hildebrandt, F. Ragaini, D. Schaarschmidt, A. Jacobi von Wangelin, ChemCatChem 2017, 9, 3203.

Iron-Catalyzed Cyclotrimerization of Terminal Alkynes by Dual Catalyst Activation in the Absence of Reductants, D. Brenna, M. Villa, T. N. Gieshoff, F. Fischer, M. Hapke, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2017, 56, 8451 (hot paper). 
Highlighted in Nachr. Chem. 2017, 65, 982.

Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts, T. N. Gieshoff, U. Chakraborty, M. Villa, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2017, 56, 3585.

Alkene Metalates as Hydrogenation Catalysts, P. Büschelberger, D. Gärtner, E. Reyes-Rodriguez, F. Kreyenschmidt, K. Koszinowski, A. Jacobi von Wangelin, R. Wolf, Chem. Eur. J. 2017, 23, 3139.

Aromatic Chlorosulfonylation by Photoredox Catalysis, M. Majek, M. Neumeier, A. Jacobi von Wangelin, ChemSusChem 201710, 151.
 

2016

Metal-free Radical Thiolations Mediated by Very Weak Bases, D. Koziakov, M. Majek, A. Jacobi von Wangelin, Org. Biomol. Chem. 2016, 14, 11347.

Mechanistic Perspectives on Organic Photoredox Catalysis for Aromatic Substitutions, M, Majek, A. Jacobi von Wangelin, Acc. Chem. Res. 2016, 49, 2316.

A Flow Reactor Setup for Photochemistry of Biphasic Gas/Liquid Reactions, J. Schachtner, P. Bayer, A. Jacobi von Wangelin, Beilstein J. Org. Chem. 2016, 12, 1198.

 

2015

Intragel Photoreduction of Aryl Halides by Green-to-Blue Upconversion under Aerobic Conditions, M. Häring, R. Perez-Ruiz, A. Jacobi von Wangelin, D. Diaz-Diaz, Chem. Commun. 2015, 51, 16848.

Application of Visible-to-UV Photon Upconversion to Photoredox Catalysis: The Activation of Aryl Bromides, M. Majek, U. Faltermeier, B. Dick, R. Perez-Ruiz, A. Jacobi von Wangelin, Chem. Eur. J. 2015, 21, 15496 (very important paper). Highlighted in Chemistry Views 2015, Sept. 20th.

Hydroaminations of Alkenes: A Radical, Revised, and Expanded Version, M. Villa, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2015, 54, 11906.

Iron-Catalyzed Cross-Coupling of Alkenyl Acetates, D. Gärtner, A. L. Stein, S. Grupe, J. Arp, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2015, 54, 10545 (hot paper). Highlighted in Nachr. Chem. 2015, 63, 974. Highlighted in Synfacts 2015, 11, 1083.

Steric Enhancement of the Chemoluminescence of Luminols, A. G. Griesbeck, Y. Diaz-Miara, R. Fichtler, A. Jacobi von Wangelin, R. Perez-Ruiz, D. Sampedro, Chem. Eur. J. 2015, 21, 9975.

Visible Light-Driven Hydro/Deutero Defunctionalization of Anilines, M. Majek, F. Filace, A. Jacobi von Wangelin, Chem. Eur. J. 2015, 21, 4518.

Iron-Catalyzed Olefin Hydrogenation at 1 bar H2 with a FeCl3/LiAlH4 Catalyst, T. N. Gieshoff, M. Villa, A. Welther, M. Plois, U. Chakraborty, R. Wolf, A. Jacobi von Wangelin, Green Chem. 2015, 17, 1408.

Metal-Free Carbonylations by Photoredox Catalysis, M. Majek, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2015, 54, 2270.

Method for Producing Aromatic Carboxylic Acid Esters, patent application, WO/2015/189374 (A1).

Verfahren zur Herstellung von aromatischen Carbonsäureestern, Patentanmeldung, DE 102014211373 (A1).

 

2014

Modular Synthesis of Cyclic cis- and trans-1,2-Diamine Derivatives, A. K. Weber, J. Schachtner, R. Fichtler, T. K. Leermann, J. M. Neudörfl, A. Jacobi von Wangelin, Org. Biomol. Chem. 2014, 12, 5267.

Reductive Cross-Coupling Reactions between Two Electrophiles, C. E. I. Knappke, S. Grupe, D. Gärtner, M. Corpet, C. Gosmini, A. Jacobi von Wangelin, Chem. Eur. J. 2014, 20, 6828.

On the Mechanism of Photocatalytic Reactions with Eosin Y, M. Majek, F. Filace, A. Jacobi von Wangelin, Beilstein J. Org. Chem. 2014, 10, 981.

Heteroatom-Free Arene Cobalt and Iron Catalysts for Hydrogenations, D. Gärtner, A. Welther, B. R. Rad, R. Wolf, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2014, 53, 3722.

Stereoselective Iron-Catalyzed Alkyne Hydrogenation in Ionic Liquids, T. N. Gieshoff, A. Welther, M. T. Kessler, M. H. G. Prechtl, A. Jacobi von Wangelin, Chem. Commun. 2014, 50, 2261.

 

2013

Highly Practical Iron-Catalyzed C-O Cleavage Reactions, D. Gärtner, H. Konnerth, A. Jacobi von Wangelin, Catal. Sci. Technol. 2013, 3, 2541.

Olefin-Assisted Iron-Catalyzed Alkylation of Aryl Chlorides, S. Gülak, T. N. Gieshoff, A. Jacobi von Wangelin, Adv. Synth. Catal. 2013, 355, 2197.

Patent: Process for Preparing Styrene Derivatives, M. Gotta, B.-W. Lehnemann, A. Jacobi von Wangelin, S. Gülak, US2013324745 (A1), 2013.

Patent: Method for Allylating and Vinylating Aryl, Heteroaryl, Alkyl, and Alkenyl Halides using Transition Metal Catalysis, M. Gotta, B.-W. Lehnemann, W. M. Czaplik, M. Mayer, A. Jacobi von Wangelin, US2013184485 (A1), 2013.

Ambient Light-Mediated Copper-Catalyzed C-C and C-N Bond FormationM. Majek, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2013, 52, 5919.

Organocatalytic Visible Light-Mediated Synthesis of Aryl Sulfides, M. Majek, A. Jacobi von Wangelin, Chem. Commun. 2013, 49, 5507.

Iron(0) Nanoparticle Catalysts in Organic Synthesis, A. Welther, A. Jacobi von Wangelin, Curr. Org. Chem. 2013, 17, 326.

Iron-Catalyzed Synthesis of Cyclopropyl Halides, S. Grupe, A. Jacobi von Wangelin, ChemCatChem 2013, 5, 706.

Highly Chemoselective Cobalt-Catalyzed Biaryl Coupling Reactions, S. Gülak, O. Stepanek, J. Malberg, B. Rezaei Rad, M. Kotora, R. Wolf, A. Jacobi von Wangelin, Chem. Sci. 2013, 4, 776.

 

2012

Development of Zn-ProPhenol-Catalyzed Asymmetric Alkyne Addition: Synthesis of Chiral Propargylic Alcohols, B. M. Trost, M. J. Bartlett, A. H. Weiss, A. Jacobi von Wangelin, V. S. Chan, Chem. Eur. J. 2012, 18, 16498.

Iron(0) Particles: Catalytic Hydrogenations and Spectroscopic Studies, A. Welther, M. Bauer, M. Mayer, A. Jacobi von Wangelin, ChemCatChem 2012, 4, 1088.

Patent: Process for Preparing Organic Compounds by a Transition Metal Catalysed Cross-Coupling reaction of an Aryl-X, Heteroaryl-X, Cycloalkenyl-X, or Alkenyl-X Compound with an Alkyl, Alkenyl, Cycloalkyl, or Cycloalkenyl Halide, M. Sundermeier, M. Gotta, A. Jacobi von Wangelin, W. M. Czaplik, US2012046471 (A1), 2012.

Oxidative N-Heterocyclic Carbene Catalysis, C. E. I. Knappke, A. Imami, A. Jacobi von Wangelin, ChemCatChem 2012, 4, 937.

Chlorostyrenes in Iron-Catalyzed Biaryl Coupling Reactions, S. Gülak, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2012, 51, 1357.

 

2011

On the Dual Role of N-Heterocyclic Carbenes as Bases and Nucleophiles in Reactions with Organic Halides, C. E. I. Knappke, A. J. Arduengo, III, H. Jiao, J.-M. Neudörfl, A. Jacobi von Wangelin, Synthesis 2011, 3784.

Iron-Catalyzed Isomerizations of Olefins, M. Mayer, A. Welther, A. Jacobi von Wangelin, ChemCatChem 2011, 3, 1567.

35 Years of Palladium-Catalyzed Cross-Coupling with Grignard Reagents: How far have we come?, C. E. I. Knappke, A. Jacobi von Wangelin, Chem. Soc. Rev. 2011, 40, 4948.

Practical Three-Component Synthesis of Crowded Arenes with Donor–Acceptor Substitution, R. Fichtler, J.-M. Neudörfl, A. Jacobi von Wangelin, Org. Biomol. Chem. 2011, 9, 7224.

On Iron-Catalyzed Reductive Aryl-Alkenyl Cross-Coupling Reactions, W. M. Czaplik, M. Mayer, A. Jacobi von Wangelin, ChemCatChem 2011, 3, 135.

Patent: Preparing Organic Compounds, e.g. cyclohexylbenzenes, comprises reacting organic compound with another organic compound in the presence of stoichiometric amount of elementary Magnesium and catalytic amounts of Transition Metal compound, M. Sundermeier, M. Gotta, A. Jacobi von Wangelin, W. M. Czaplik, ES2369961 (T3), 2011.

 

2010

The Aminohydroxylation of Alkenes Breaks New Grounds, C. E. I. Knappke, A. Jacobi von Wangelin, ChemCatChem 2010, 2, 1381.

Practical Iron-Catalyzed Dehalogenation of Aryl Halides, W. M. Czaplik, S. Grupe, M. Mayer, A. Jacobi von Wangelin, Chem. Commun. 2010, 46, 6350.

Practical Iron-Catalyzed Allylations of Aryl Grignard Reagents, M. Mayer, W. M. Czaplik, A. Jacobi von Wangelin, Adv. Synth. Catal. 2010, 352, 2147.

On Direct Iron-Catalyzed Cross-Coupling Reactions, W. M. Czaplik, M. Mayer, S. Grupe, A. Jacobi von Wangelin, Pure Appl. Chem. 2010, 82, 1545.

A Synthetic Double Punch: Suzuki-Miyaura Cross-Coupling Mates with CH Functionalization, C. E. I. Knappke, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2010, 49, 3568.

On New N-Heterocyclic Carbene Derived Alkylidene Imidazolines, C. E. I. Knappke, J. M. Neudörfl, A. Jacobi von Wangelin, Org. Biomol. Chem. 2010, 8, 1695.

On the Photophysical Properties of New Luminol Derivatives and their Synthetic Phthalimide Precursors, R. Pérez-Ruiz, R. Fichtler, Y. Diaz Miara, M. Nicoul, D. Schaniel, H. Neumann, M. Beller, D. Blunk, A. G. Griesbeck, A. Jacobi von Wangelin,  J. Fluoresc. 2010, 20, 657.

Patent: Preparing Organic Compounds, e.g. functionalized Aryl compounds, comprises reacting Aryl compounds with Halide-containing Alkyl compounds in the presence of elemental Magnesium, Transition Metal compound and Nitrogen-containing additive, M. Sundermeier, M. Gotta, A. Jacobi von Wangelin, W. M. Czaplik, DE102008062690 (A1), 2010.

 

2009

Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions, W. M. Czaplik, M. Mayer, J. Cvengros, A. Jacobi von Wangelin, ChemSusChem 2009, 2, 396.

Direct Cobalt-Catalyzed Cross-Coupling Between Aryl and Alkyl Halides, W. M. Czaplik, M. Mayer, A. Jacobi von Wangelin, Synlett 2009, 2931.

On Cobalt-Catalyzed Biaryl Coupling Reactions, M. Mayer, W. M. Czaplik, A. Jacobi von Wangelin, Synlett 2009, 2919.

Domino Iron Catalysis: Direct Aryl-Alkyl Cross-Coupling, W. M. Czaplik, M. Mayer, A. Jacobi von Wangelin, Angew. Chem. Int. Ed. 2009, 48, 607 (VIP).

Amidocarbonylations, H. Neumann, A. Jacobi von Wangelin, M. Beller, in Encyclopedia of Catalysis, I. T. Horvath, E. Iglesia, M. T. Klein, J. A. Lercher, A. J. Russel, E. I. Stiefel (eds.), 2nd ed., Wiley: New York, 2009.

 

1999-2008

Beyond Wishful Thinking and Sweet Dreams, A. Jacobi von Wangelin, ChemSusChem 2008, 1, 565.

On the Quantitative Recycling of Raney-Nickel Catalysts On a Lab Scale, W. M. Czaplik, J.-M. Neudörfl, A. Jacobi von Wangelin, Green. Chem. 2007, 1163.

Hydroxymethylpyridine Catalysts for the Enantioselective Alkynylation of Aldehydes, S. Liebehentschel, J. Cvengros, A. Jacobi von Wangelin, Synlett 2007, 2574.

Three Component Reactions of α- and β-Bromo Aldehydes with Amides and Dienophiles – An Easy Way to Versatile 1-Amido-2-Cyclohexenes, S. Hübner, H. Neumann, D. Michalik, S. Klaus, D. Strübing, A. Spannenberg, A. Jacobi von Wangelin, M. Beller, Synlett 2007, 1085.

An Easy and General Protocol for Multicomponent Coupling Reactions of Amides, Aldehydes and Dienophiles, D. Strübing, H. Neumann, A. Jacobi von Wangelin, S. Klaus, S. Hübner, M. Beller, Tetrahedron 2006, 62, 10962.

A Dinuclear Zinc Catalyzed Asymmetric Alkynylation of Unsaturated Aldehydes, B. M. Trost, A. H. Weiss, A. Jacobi von Wangelin,  J. Am. Chem. Soc. 2006, 128, 8.

Carbonylation of Aldehydes, A. Jacobi von Wangelin, H. Neumann, M. Beller, in Catalytic Carbonylation Reactions, Top. Organomet. Chem., Vol. 18, Springer: Berlin, 2006, p207.

Efficient One-Pot Synthesis of Substituted 1-Acylaminocyclohex-2-enes, S. Hübner, H. Neumann, A. Jacobi von Wangelin, S. Klaus, D. Strübing, H. Klein, M. Beller, Synthesis 2005, 2084, 2270.

Sequential Three-Component and Heck Reactions for the Synthesis of Phenanthridones, A. Jacobi von Wangelin, H. Neumann, D. Gördes, S. Hübner, C. Wendler, S. Klaus, D. Strübing, A. Spannenberg, H. Jiao, L. El Firdoussi, K. Thurow, N. Stoll, M. Beller, Synthesis 2005, 2029.

Multicomponent Reaction of Aldehydes, Anhydrides, and Dienophiles: Synthesis of „Butterfly“-like Diazatetradecenes, D. Strübing, A. Jacobi von Wangelin, H. Neumann, D. Gördes, S. Hübner, S. Klaus, A. Spannenberg, M. Beller, Eur. J. Org. Chem. 2005, 107.

Efficient Hydroalkoxycarbonylation of Enamides to N-Acyl Amino Acid Esters: Theoretical Studies and Synthetic Applications, S. Klaus, H. Neumann, H. Jiao, A. Jacobi von Wangelin, D. Gördes, D. Strübing, S. Hübner, M. Hateley, C. Weckbecker, T. Riermeier, M. Beller, J. Organomet. Chem. 2004, 689, 3685.

Second Generation Protocol for Multicomponent Coupling Reactions of Aldehydes, Amides, and Dienophiles, S. Klaus, S. Hübner, H. Neumann, D. Strübing, A. Jacobi von Wangelin, D. Gördes, M. Beller, Adv. Synth. Catal. 2004, 346, 970.

A New Efficient Synthesis of Substituted Luminols Using Multicomponent Reactions, H. Neumann, S. Klaus, M. Klawonn, D. Strübing, S. Hübner, D. Gördes, A. Jacobi von Wangelin, M. Lalk, M. Beller, Z. Naturforsch. 2004, 59b, 431.

From a Spin-Off to the Advantageous Use in Diels-Alder Reactions: A Combined Synthetic, Spectroscopic and Computational Approach to N-(Dienyl)acylamines, D. Gördes, A. Jacobi von Wangelin, S. Klaus, H. Neumann, D. Strübing, S. Hübner, H. Jiao, W. Baumann, M. Beller, Org. Biomol. Chem. 2004, 2, 845.

Enzymatic Resolution of 4-N-Phenylacetylamino Derivatives Obtained from Multicomponent Reactions Using PenG Amidase and In-Silico Studies, D. Strübing, H. Neumann, S. Klaus, A. Jacobi von Wangelin, D. Gördes, M. Beller, P. Braiuca, C. Ebert, L. Gardossi, U. Kragl, Tetrahedron 2004, 60, 683.

Amidocarbonylation of Aldehydes, A. Jacobi von Wangelin, H. Neumann, M. Beller, in Transition Metals for Organic Synthesis, M. Beller, C. Bolm (eds.), Wiley-VCH: Weinheim, 2004, p133.

Bismuth Reagents and Catalysts in Organic Synthesis, A. Jacobi von Wangelin, in Transition Metals for Organic Synthesis, M. Beller, C. Bolm (eds.), Wiley-VCH: Weinheim, 2004, p379.

Zinc-mediated Reactions, A. Jacobi von Wangelin, M. U. Frederiksen, in Transition Metals for Organic Synthesis, M. Beller, C. Bolm (eds.), Wiley-VCH: Weinheim, 2004, p519.

Patent: M. Beller, H. Neumann, A. Jacobi von Wangelin, D. Gördes, DE10137740 (A1), 2003.

Patent: M. Beller, H. Neumann, A. Jacobi von Wangelin, D. Gördes, DE10137739 (A1), 2003.

Patent: M. Beller, H. Neumann, A. Jacobi von Wangelin, D. Gördes, DE10137731 (A1), 2003.

Anilines Made Easily: From Aldehydes to Tri-, Tetra-, and Penta-substituted Anilines in Two Steps, H. Neumann, A. Jacobi von Wangelin, S. Klaus, D. Strübing, D. Gördes, M. Beller, Angew. Chem. Int. Ed. 2003, 42, 4503.

Multicomponent Coupling Reactions for Organic Synthesis: Chemoselective Reactions with Amide-Aldehyde Mixtures, A. Jacobi von Wangelin, H. Neumann, D. Gördes, S. Klaus, D. Strübing, M. Beller, Chem. Eur. J. 2003, 9, 4286.

Unusual Coupling Reactions of Aldehydes and Alkynes: A Novel Preparation of Substituted Phthalic Acid Derivatives by Automated Synthesis, A. Jacobi von Wangelin, H. Neumann, D. Gördes, S. Klaus, H. Jiao, A. Spannenberg, T. Krüger, C. Wendler, K. Thurow, N. Stoll, M. Beller, Chem. Eur. J. 2003, 9, 2273.

Synthesis of N-Acetyl α-Aminobutyric Acid via Amidocarbonylation: A Case Study, D. Gördes, H. Neumann, A. Jacobi von Wangelin, C. Fischer, K. Drauz, H.-P. Krimmer, M. Beller, Adv. Synth. Catal. 2003, 345, 510.

Multicomponent Coupling Reactions of Aldehydes and Amides with Maleic Anhydride: Synthesis of 7-Oxo-6-azabicyclo[3.2.1]oct-2-ene-8-carboxylic Acid Derivatives, H. Neumann, A. Jacobi von Wangelin, D. Gördes, A. Spannenberg, W. Baumann, M. Beller, Tetrahedron 2002, 58, 2381.

Maximizing Synthetic Efficiency: The Development of New Multicomponent Reactions, A. Jacobi von Wangelin, Ph.D. Thesis, University of Rostock, 2002.

A Facile Three-Component Coupling Procedure for the Synthesis of Substituted Tetrahydroisoindole-1,3-diones from α,β-Unsaturated Aldehydes, A. Jacobi von Wangelin, H. Neumann, D. Gördes, A. Spannenberg, M. Beller, Org. Lett. 2001, 3, 2895.

A New Multicomponent Coupling of Aldehydes, Amides, and Dienophiles: Atom-Efficient One-Pot Synthesis of Highly Substituted Cyclohexenes and Cyclohexadienes, H. Neumann, A. Jacobi von Wangelin, D. Gördes, A. Spannenberg, M. Beller, J. Am. Chem. Soc. 2001, 123, 8398.

Synthesis and Characterization of Novel Rhenium π- and σ-Alkyne Complexes: Investigations into Possible Applications to Electron-Transfer Processes and towards Molecular Devices, A. Jacobi von Wangelin, Master Thesis, University of Erlangen-Nürnberg, 1999.

  1. Faculty of Chemistry and Pharmacy
  2. Institute of Organic Chemistry

Research Group
Axel Jacobi von Wangelin

Prof. Dr.
Axel Jacobi von Wangelin

 

Institute of Organic Chemistry
University of Regensburg

Universitaetsstr. 31
93040 Regensburg
Germany

Phone +49 (0)941 943-4802
Fax +49 (0)941 943-4617