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Publications

2017


56.- T. Fischer, Q.-N. Duong, O. García Mancheño,*  

Triazole-based Anion-binding Catalysis for the Enantioselective Dearomatization of N-Heteroarenes with P-Nucleophiles”. Chem. Eur. J. 2017, 23, 5983-5987.

DOI: 10.1002/chem.201605660.

 

55.- A. Gini, T. Brandhofer, O. García Mancheño,*    

Recent progress on mild oxidative Csp3-H bond functionalization”. Org. Biomol. Chem. 2017, 15, 1294- 1312. DOI: 10.1039/c6ob02474b. (Review Article)

 

 

54.- M. Zurro, O. García Mancheño,*    

1,2,3-Triazole-Based Catalysts: From Asymmetric Metal Catalysis to Anion-Binding Organocatalysis”.  Chem. Rec. 201717, 485-498. DOI: 10.1002/tcr.201600104

53.- S. Stockerl, D. Gutiérrez, O. García Mancheño,*    

Click-BINOL-Phosphoric Acid Catalysts in Intramolecular enantioselective Oxidative    C-H-Bond Functionalization”. J. Mol. Catal. A: Chem. 2017, 426, Part B, 572-585

DOI: 10.1016/j.molcata.2016.09.006

 

 2016


52.- A. Gini, J. Bamberger, J. Luis-Barrera, M. Zurro, R. Mas-Ballesté, J. Alemán,* O. García Mancheño,* 

“Synthesis of 3-Benzazepines by Metal-free Oxidative C–H Bond Functionalization–Ring Expansion Tandem Reaction”. Adv. Synth. Catal. 2016, 358, 4049-4056.  DOI: 10.1002/adsc.201600985

 

 

51.- O. García Mancheño,*    

Book review: Sustainable Catalysis. Without Metals or Other Endangered Elements”, Part 1 and 2 Edited by Michael North. Angew. Chem. Int. Ed. 2016, 55, 15955. 

 

50.- O. García Mancheño,*    

"Mimicking Nature: Anion-Binding Processes for Cooperative Catalysis".  International Innovation 2016, 202, 72-73. 

http://digimag.internationalinnovation.com//launch.aspx?eid=b13272f8-e2cd-4ebd-bc30-11bcc3b71dd7

 

49.- T. Fischer, J. Bamberger, O. García Mancheño,*    

Asymmetric Nucleophilic Dearomatization of Diazarenes by Anion-Binding Catalysis”. Org. Biomol. Chem. 2016, 14, 5794-5802. DOI: 10.1039/c6ob00248j 

    

   


48.- M. Zurro, S. Asmus, J. Bamberger, S. Beckendorf, O. García Mancheño,
*    

Chiral Triazoles in Anion-Binding Catalysis: New Entry to Enantioselective Reissert-Type Reactions”.

Chem. Eur. J 2016, 22, 3785-3793. DOI:10.1002/chem.201504094.     

   (Woman in Chemistry Issue)

 

 

47.- S. Stockerl, O. García Mancheño,*    

Non-Covalent Organocatalysis in Asymmetric Oxidative C(sp3)-H Bond Functionalization - Broadening C-H Bond Coupling Reactions”.

Org. Chem. Front. 2016, 3, 277-280.


46.- A. Gini, O. García Mancheño,
*    

Mild Radical Oxidative C(sp3)-H Functionalization: Innovative Construction of Isoxazolines and Dibenz[b,f]oxepines/azepines”.

Synlett 2016, 27, 526-539 DOI: 10.1055/s-0035-1560908. (Account)
 TOC-Account1

 

2015

 

45.- A. Gini, M. Segler, D. Kellner, O. García Mancheño,*   

“Dehydrogenative TEMPO-Mediated Formation of Unstable Nitrones: Easy Access to N-Carbamoyl Isoxazolines”.

 Chem. Eur. J. 2015, 21, 12053-12060. DOI: 10.1002/chem.201501314.
 (HOT PAPER)
 


 

44. O. García Mancheño,* S. Asmus, M. Zurro, T. Fischer,  

“Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion-Binding Catalysis”.

Angew. Chem. Int. Ed. 2015, 54, 8823-8827. DOI: 10.1002/anie.201502708

 

 

 

43.- T. Stopka, L. Marzo, M. Zurro, S. Janich, E.-U. Würthwein, C. G. Daniliuc, J. Alemán,* O. García Mancheño,*   

“Oxidative C-H Bond Functionalization-Ring Expansion Reaction with TMSCHN2: A novel Cu(I)-Catalyzed Approach to Dibenzoxe- and Dibenzoazepines”.

 Angew. Chem. Int. Ed. 2015, 54, 5049-5053. 



 
 

2014

 

42.- M. Zurro, S. AsmusS. Beckendorf, C. Mück-Lichtenfeld,O. García Mancheño,*   

Chiral Helical Oligotriazoles: New Class of Anion-Binding Catalysts for the Asymmetric Dearomatization of Electron-Deficient N-Heteroarenes”.

 J. Am. Chem. Soc. 2014, 136, 13999-14002
 

(Highlighted in SYNFACTS 2014, 10, 1321)

(Highlighted in Nachrichten aus der Chemie 12/2014, pp 1160)

 
 
Figure

 

41.- S. Asmus, S. Beckendorf, M. Zurro, C. Mück-Lichtenfeld, R. Fröhlich, O. García Mancheño,*     

Influence of the Substitution and Conformation of C−H Bond-Based BisTriazole Acceptors in Anion-Binding Catalysis”.

Chem. Asian J. 2014,  9, 2178-2186

 

Link to full-size graphical abstract


 2013


40.- R. Rohlmann, C. G. Daniliuc, O. García Mancheño,*     

“Highly Enantioselective Synthesis of Chiral 7-Ring O- an N-Heterocycles by a One-pot Nitro-Michael/Cyclization Tandem Reaction”. 

Chem. Commun. 2013, 49, 11665-11667.

 

Graphical abstract: Highly enantioselective synthesis of chiral 7-ring O- and N-heterocycles by a one-pot nitro-Michael–cyclization tandem reaction

 

39.- R. Rohlmann, T. Stopka, H. Richter, O. García Mancheño,*     

“Iron-Catalyzed Oxidative Tandem Reactions with TEMPO Oxoammonium Salts: Synthesis of Dihydroquinazolines and Quinolines”.

J. Org. Chem.2013, 78, 6050-6064.

 

Abstract Image

 

38.-  T. Stopka, O. García Mancheño,*    

“TEMPO Derivatives as Alternative Mild Oxidants in C–C Coupling Reactions”.

Synthesis 2013, 45, 1602-1611 (Invited Review).

 

https://www.thieme-connect.de/media/synthesis/201312/i_e0241_ga_10-1055_s-0033-1338480.gif

 

37.-“Young Career Focus: Dr. Olga García Mancheño”. SYNFORM, 2013/01, Synstories A12; DOI: 10.1055/s-0032-1317679.

 

36.- S. Beckendorf, S. Asmus, C. Mück-Lichtenfeld, O. García Mancheño,*     

“Click-BisTriazoles as Neutral C−H—Anion Acceptor Organocatalysts”. 

Chem. Eur. J. 2013, 19, 1581-1585.

Highlighted in SynFacts: “Hydrogen-Bonding Catalysis using C-HX Interactions”, Synfacts 2013, 9, 327.

 

 

35.- R. Rohlmann, O. García Mancheño,*    

“Metal-Free Oxidative C(sp3)–H Bond Couplings as Valuable Synthetic Tools for C–C Bond Formations”

Synlett 2013, 24, 6-10.

 

https://www.thieme-connect.de/media/synlett/201301/p0857_ga.gif


2012


34.- H. Richter, R. Fröhlich, C. G. Daniliuc, O. García Mancheño,*     

“Mild Metal-free Tandem α-Alkylation/Cyclization of N-Benzyl Carbamates with Simple Olefins”

Angew. Chem. Int. Ed. 2012, 51, 8656-8660.

Highlighted in SynFacts: “Synthesis of Methopholine”, Synfacts 2012, 8, 1172.

 

Link to full-size graphical abstract

 

33.- O. García Mancheño,* M. Alcarazo,*     

“At the Frontiers of Knowledge in Chemistry: The 47th Bürgenstock Conference”. 

Angew. Chem. Int. Ed. 2012, 51, 8151-8154. (Meeting Reviews)

 

32.-R. Rohlmann, O. García Mancheño,*                 

“Sulfur Activated α-Methylene Reagents in Asymmetric Catalysis”.

Current Org. Chem. 2012, 16, 2160-2191 (special issue on Active Methylene Compounds).

 

31.-S. Beckendorf, O. García Mancheño,*                

“Click-BINOLs: New Class of Tunable Ligands for Asymmetric Catalysis”

Synthesis 2012, 44, 2162-2172(special topic on Lewis Acid Catalysis).

 

https://www.thieme-connect.de/media/synthesis/201214/c0311_ga.gif

 

30.- S. Beckendorf, S. Asmus, O. García Mancheño,*    

“H-Donor Anion Acceptor Organocatalysis – The Ionic Electrophile Activation Approach”.

 ChemCatChem 2012, 4, 926-936 (special issue on Organocatalysis).

 

 

29.-V. More, R. Rohlmann, O. García Mancheño,* C. Petronzi, L. Palombi, V. Intintoli, A. Massa,*                 

“First Organocatalytic Asymmetric Synthesis of 3-Substituted Isoindolinones”. 

RSC Adv. 2012, 2, 3592-3595.

 


2011


 28.- H. Richter, O. García Mancheño,*

“TEMPO Oxoammoninum Salt Mediated Dehydrogenative Povarov – Oxidation Tandem Reaction of N-Alkyl Anilines”.

Org. Lett. 2011, 13, 6066-6069.

 Highlighted in SynFacts: “Synthesis of Quinolines from N-Alkyl Anilines and Olefins”, Synfacts 2012, 8, 139.

 

 

27.- H. Richter, R. Rohlmann, O. García Mancheño,*

“Catalyzed Selective Direct a- and g-Alkylation of Aldehydes with Cyclic Benzyl Ethers Using T+BF4- in the Presence of an Inexpensive Organic Acid or Anhydride”.

Chem. Eur. J. 2011, 17, 11622-11627.

 

Link to full-size graphical abstract

 

26.- H. Richter, S. Beckendorf, O. García Mancheño,*

“Modifiable Sulfur Tethers as Directing Groups for Aromatic C–H Acetoxylation Reactions”.

Adv. Synth. Catal. 2011, 353, 295-302.

 

 

25.- O. García Mancheño,*

“New Trends Towards Well-Defined Low-Valent Iron Catalysis” / “Neue Trends bei der Katalyse mit definierten niedervalenten Eisenkomplexen”. 

Angew. Chem. Int. Ed. 2011, 50, 2216-2218; Angew. Chem. 2011, 123, 2264-2266.

 

24.- O. García Mancheño,* P. Tangen, R. Rohlmann, R. Fröhlich,J. Alemán,*

"Synthesis of Chiral Cyclic Nitrones by Asymmetric Addition of β-Ketosulfones to Nitroalkenes followed by Reductive Cyclization”.

Chem. Eur. J. 2011, 17, 984-992.

 Highlighted in SynFacts: “Michael Addition of β-ketosulfones to Nitroalkenes”, Synfacts 2011, 7, 218

 

 


 

23.- H. Richter, O. García Mancheño,*

“Dehydrogenative Functionalization of C(sp3)–H Bonds Adjacent to a Heteroatom Mediated by Oxoammonium Salts”.

Eur. J. Org. Chem. 2010, 4460-4467.

 

Link to full-size graphical abstract


 


Postdoc

 22.- A. G. Pandey, M. J. McGrath, O. García Mancheño, C. Bolm,*

“Asymmetric Syntheses of S,S-Dialkyl-Substituted Sulfoximines and Related Heterocycles”.

Synthesis 2011, 3827-3838.

 

21.- O. García Mancheño, J. Dallimore, A. Plant, C. Bolm,*

 “Synthesis of Sulfoximines and Sulfilimines with Aryl and Pyrazolylmethyl Substituents”.

 Adv. Synth. Catal. 2010, 352, 309-316.

 

20.- O. García Mancheño, J. Dallimore, A. Plant,C. Bolm,*

"Iron(II) Triflate asan Efficient Catalysts for the Imination of Sulfoxides"

Org. Lett. 2009, 11, 2429-2432.

 

19.- A. Correa, O. García Mancheño, C. Bolm,*                

“Iron-catalyzed Carbon-Heteroatom and Heteroatom-Heteroatom Bond Forming Processes”. 

Chem. Soc. Rev. 2008, 37, 1108-1117. (Cover Picture)

 

18.- O. García Mancheño, C. Bolm,*

"Synthesisof Sulfonimidamides from Sulfinamides by Oxidation with N-Chlorosuccinimide"

 Beilstein J. Org. Chem. 2007, 3, 25.

 

17.- O. García Mancheño, O. Bistri, C. Bolm,*

“Iodinane- and Metal-free Synthesis of N-Cyano Sulfilimines: Novel and Easy Access to NH-Sulfoximines”. 

Org. Lett. 2007, 9, 3809-3811.

 

16.- O. García Mancheño, C. Bolm,*                            

“Synthesis of N-(1H)-Tetrazole Sulfoximines”. 

Org. Lett. 2007, 9, 2951-2954.

 Highlighted in SynFacts: “Synthesis of Tetrazole and Oxadiazole Sulfoximines”, Synfacts 2007, 1026.

 

15.- O. García Mancheño, C. Bolm,*                              

“Comparative Study of Metal-Catalyzed Iminations of Sulfoxides and Sulfides”.

Chem. Eur. J. 2007, 13, 6674-6681.

 

14.-O. García Mancheño, C. Bolm,*

“Iron-Catalyzed Imination of Sulfoxides and Sulfides”.

Org. Lett. 2006, 8, 2349-2352.

 


 

PhD Thesis

 13.- O. García Mancheño, R. Gómez Arrayás, J. Adrio, J. C. Carretero,*

“Catalytic Enantioselective Approach to the Stereodivergent Synthesis of (+)-Lasubines I and II”. 

J. Org. Chem. 2007, 72, 10294-10297.

 

12.- S. Cabrera, O. García Mancheño, R. Gómez Arrayás, I. Alonso, P. Mauleón, J. C. Carretero,*

Sulfenylphosphinoferrocenes: Novel Planar Chiral Ligands in Enantioselective Catalysis”.          

Pure & Appl. Chem. 2006, 78, 257-266.

 

11.- O. García Mancheño, R. Gómez Arrayás, J. C. Carretero,*                              Copper(I) Complexes of Fesulphos Ligands: Highly Efficient Chiral Lewis Acids for the Formal Aza Diels-Alder Reaction of N-Sulfonyl Imines”.

Phosphorus, Sulfur and Silicon & Related Elem. 2005, 180, 1515-1516.

 

10.- R. Gómez Arrayás, O. García Mancheño, S. Cabrera, J. C. Carretero,*

“Transition Metal Complexes of Fesulphos Ligands in Enantioselective Catalytic Transformations”.

Phosphorus, Sulfur and Silicon & Related Elem. 2005, 180, 1259-1265.

 

9.- O. García Mancheño, R. Gómez Arrayás, J. C. Carretero,*

Palladium Complexes of Chiral Planar 1-Phosphino-2-sulfenylferrocenes as Efficient Catalysts in Enantioselective Diels-Alder Reactions".

Organometallics 2005, 24, 557-561.

 

8.- M. R. Acocella, O. García Mancheño, M. Bella, K. A. Jørgensen,*

“Organocatalytic Asymmetric Hydroxylation of β-Keto Esters – Metal-Free Synthesis of Optically Active anti-Diols”. 

J. Org. Chem. 2004, 69, 8165-8167.

 

7.-O. García Mancheño, R. Gómez Arrayás, J. C. Carretero,*

Chiral Copper Complexes of Phosphino Sulfenyl Ferrocenes as Efficient Catalysts for Enantioselective Formal Aza Diels-Alder Reactions of N-Sulfonyl Imines.” 

J. Am. Chem. Soc. 2004, 126, 456-457.

 

6.-R. Gómez Arrayás, O. García Mancheño, J. C. Carretero,*

First Planar Chiral Bidentate Ligand Based on a (η5-cyclopentadienyl)(η4-cyclobutadiene) Cobalt Skeleton: High Efficiency in Enantioselective Palladium-catalyzed Allylic Substitutions”. 

Chem. Commun. 2004, 1654-1655.

 

5.- O. García Mancheño, J. Priego, S. Cabrera, R. Gómez Arrayás, T. Llamas, J. C. Carretero,*

1-Phosphino-2-sulfenylferrocenes as Planar Chiral Ligands in Enantioselective Palladium-catalyzed Allylic Substitutions”.

J. Org. Chem. 2003, 68, 3679-3686.

 

4.-J. Priego, O. García Mancheño, S. Cabrera, R. Gómez Arrayás, T. Llamas, J. C. Carretero,*

“1-Phosphino-2-sulfenylferrocenes: Efficient Ligands in Enantioselective Palladium-catalyzed Allylic Substitutions and Ring Opening of 7-Oxabenzonorbornadienes”.

Chem. Commun. 2002, 2512-2513.

 


 

Master Thesis

 3.-J. Priego, O. García Mancheño, S. Cabrera, J. C. Carretero,*

“2-Aminosubstituted 1-Sulfinylferrocenes as Chiral Ligands in the Addition of Diethylzinc to Aromatic Aldehydes”. 

J. Org. Chem. 2002, 67, 1346-1353.

 

2.-J. Priego, O. García Mancheño, S. Cabrera, J. C. Carretero,*

“Aminosubstituted t-Butylsulfinylferrocenes as a New Family of Chiral Ligands: Asymmetric Addition of Diethylzinc to Aldehydes”.

Chem. Commun. 2001, 2026-2027.

 

1.-N. Díaz Buezo, O. García Mancheño, J. C. Carretero,*

The 2-(N,N-Dimethylamino)phenylsulfinil Group as an Efficient Chiral Auxiliary in Intramolecular Heck Reactions”

Org. Lett. 2000, 2, 1451-1452.


  1. Fakulty of Chemistry and Pharmacy
  2. Institute of Organic Chemistry

Research Group
Garcia Mancheño

Prof. Dr.
Olga Garcia Mancheño

 

Office

Building CH, room 22.0.83

Phone ++941 943-4501
Fax ++941 943-1717
E-mail